The hydrogen atom channel in the photodissociation of HNCO

Whikun Yi, Richard Bersohn

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

In the photodissociation of HNCO at 193.3 and 212.6 nm the main channel is NH(a 1Δ) + CO but the channel H + NCO has also been observed with a yield of 0.050±0.006 at 193.3 nm and 0.13±0.01 at 212.6 nm. The average kinetic energy of the H atoms at 193.3 and 212.6 nm is 10.7±1.5 and 11.4±0.6 kcal/mol respectively. Results are compared with similar data recently reported for HN3.

Original languageEnglish
Pages (from-to)365-368
Number of pages4
JournalChemical Physics Letters
Volume206
Issue number1-4
DOIs
StatePublished - 1993 Apr 30

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Photodissociation
Carbon Monoxide
Kinetic energy
photodissociation
Hydrogen
hydrogen atoms
Atoms
kinetic energy
atoms

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Yi, Whikun ; Bersohn, Richard. / The hydrogen atom channel in the photodissociation of HNCO. In: Chemical Physics Letters. 1993 ; Vol. 206, No. 1-4. pp. 365-368.
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The hydrogen atom channel in the photodissociation of HNCO. / Yi, Whikun; Bersohn, Richard.

In: Chemical Physics Letters, Vol. 206, No. 1-4, 30.04.1993, p. 365-368.

Research output: Contribution to journalArticle

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AB - In the photodissociation of HNCO at 193.3 and 212.6 nm the main channel is NH(a 1Δ) + CO but the channel H + NCO has also been observed with a yield of 0.050±0.006 at 193.3 nm and 0.13±0.01 at 212.6 nm. The average kinetic energy of the H atoms at 193.3 and 212.6 nm is 10.7±1.5 and 11.4±0.6 kcal/mol respectively. Results are compared with similar data recently reported for HN3.

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