The effect of acceptor-substituted alkynes in gold-catalyzed intermolecular reactions

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Abstract

Alkynes substituted with electron-withdrawing groups participated in various intermolecular reactions with olefin substrates, including [4 + 2] annulation of propiolic acids, intermolecular metathesis-type reaction and carboalkoxylation involving allylethers.

Original languageEnglish
Pages (from-to)373-379
Number of pages7
JournalPure and Applied Chemistry
Volume86
Issue number3
DOIs
StatePublished - 2014 Mar 20

Keywords

  • OMCOS-17
  • alkenes
  • alkynes
  • annulations
  • atom economy
  • carboalkoxylation
  • catalysis
  • enyne cross-metathesis
  • gold catalysis
  • intermolecular reactions

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