Synthesis of cyclohexene derivatives from 1,5-enynes via gold-catalysis and iodocyclization: A comparative study and applications in the synthesis of 7/5- or 8/5-fused rings and biaryls

Youngun Lee, Choongmin Lim, Sunghwan Kim, Seunghoon Shin

Research output: Contribution to journalArticle

11 Scopus citations

Abstract

A comparative study on the Au(I)-catalyzed and IBr-promoted tandem cyclization of 1,5-enyne was reported. This study provides a meaningful mechanistic insight to the concerted nature of this tandem reaction and also provides interesting applications in the synthesis of 7/5- or 8/5-fused bicycles and biaryls.

Original languageEnglish
Pages (from-to)670-677
Number of pages8
JournalBulletin of the Korean Chemical Society
Volume31
Issue number3
DOIs
StatePublished - 2010 Mar 1

Keywords

  • 1,5-enyne
  • Carbocycles
  • Gold catalysis
  • Iodocyclization
  • Tandem reaction

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