Abstract
A highly effective silver(I)-mediated C-H amination of 2-alkenylanilines has been developed to afford a diverse range of substituted indoles. High functional group tolerance, broad substrate scope, simple/fast/high-yielding reaction, and recovery/reuse of the inexpensive silver oxidant are noteworthy. Furthermore, an uncommon migratory process of β-monosubstituted 2-alkenylanilines with solvent-dependence was demonstrated.
| Original language | English |
|---|---|
| Pages (from-to) | 227-234 |
| Number of pages | 8 |
| Journal | Advanced Synthesis and Catalysis |
| Volume | 357 |
| Issue number | 1 |
| DOIs | |
| State | Published - 2015 Dec 22 |
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Keywords
- Cyclization
- Indoles
- Migration
- Oxidation
- Silver
Cite this
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Silver(I)-mediated C-H amination of 2-alkenylanilines : Unique solvent-dependent migratory aptitude. / Youn, So Won; Ko, Tae Yun; Jang, Min Jung; Jang, Su San.
In: Advanced Synthesis and Catalysis, Vol. 357, No. 1, 22.12.2015, p. 227-234.Research output: Contribution to journal › Review article
TY - JOUR
T1 - Silver(I)-mediated C-H amination of 2-alkenylanilines
T2 - Unique solvent-dependent migratory aptitude
AU - Youn, So Won
AU - Ko, Tae Yun
AU - Jang, Min Jung
AU - Jang, Su San
PY - 2015/12/22
Y1 - 2015/12/22
N2 - A highly effective silver(I)-mediated C-H amination of 2-alkenylanilines has been developed to afford a diverse range of substituted indoles. High functional group tolerance, broad substrate scope, simple/fast/high-yielding reaction, and recovery/reuse of the inexpensive silver oxidant are noteworthy. Furthermore, an uncommon migratory process of β-monosubstituted 2-alkenylanilines with solvent-dependence was demonstrated.
AB - A highly effective silver(I)-mediated C-H amination of 2-alkenylanilines has been developed to afford a diverse range of substituted indoles. High functional group tolerance, broad substrate scope, simple/fast/high-yielding reaction, and recovery/reuse of the inexpensive silver oxidant are noteworthy. Furthermore, an uncommon migratory process of β-monosubstituted 2-alkenylanilines with solvent-dependence was demonstrated.
KW - Cyclization
KW - Indoles
KW - Migration
KW - Oxidation
KW - Silver
UR - http://www.scopus.com/inward/record.url?scp=84920717918&partnerID=8YFLogxK
U2 - 10.1002/adsc.201400759
DO - 10.1002/adsc.201400759
M3 - Review article
AN - SCOPUS:84920717918
VL - 357
SP - 227
EP - 234
JO - Advanced Synthesis and Catalysis
JF - Advanced Synthesis and Catalysis
SN - 1615-4150
IS - 1
ER -