Silver(I)-mediated C-H amination of 2-alkenylanilines: Unique solvent-dependent migratory aptitude

So Won Youn, Tae Yun Ko, Min Jung Jang, Su San Jang

Research output: Contribution to journalReview article

25 Citations (Scopus)

Abstract

A highly effective silver(I)-mediated C-H amination of 2-alkenylanilines has been developed to afford a diverse range of substituted indoles. High functional group tolerance, broad substrate scope, simple/fast/high-yielding reaction, and recovery/reuse of the inexpensive silver oxidant are noteworthy. Furthermore, an uncommon migratory process of β-monosubstituted 2-alkenylanilines with solvent-dependence was demonstrated.

Original languageEnglish
Pages (from-to)227-234
Number of pages8
JournalAdvanced Synthesis and Catalysis
Volume357
Issue number1
DOIs
StatePublished - 2015 Dec 22

Fingerprint

Amination
Silver
Indoles
Oxidants
Functional groups
Recovery
Substrates

Keywords

  • Cyclization
  • Indoles
  • Migration
  • Oxidation
  • Silver

Cite this

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abstract = "A highly effective silver(I)-mediated C-H amination of 2-alkenylanilines has been developed to afford a diverse range of substituted indoles. High functional group tolerance, broad substrate scope, simple/fast/high-yielding reaction, and recovery/reuse of the inexpensive silver oxidant are noteworthy. Furthermore, an uncommon migratory process of β-monosubstituted 2-alkenylanilines with solvent-dependence was demonstrated.",
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Silver(I)-mediated C-H amination of 2-alkenylanilines : Unique solvent-dependent migratory aptitude. / Youn, So Won; Ko, Tae Yun; Jang, Min Jung; Jang, Su San.

In: Advanced Synthesis and Catalysis, Vol. 357, No. 1, 22.12.2015, p. 227-234.

Research output: Contribution to journalReview article

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T2 - Unique solvent-dependent migratory aptitude

AU - Youn, So Won

AU - Ko, Tae Yun

AU - Jang, Min Jung

AU - Jang, Su San

PY - 2015/12/22

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N2 - A highly effective silver(I)-mediated C-H amination of 2-alkenylanilines has been developed to afford a diverse range of substituted indoles. High functional group tolerance, broad substrate scope, simple/fast/high-yielding reaction, and recovery/reuse of the inexpensive silver oxidant are noteworthy. Furthermore, an uncommon migratory process of β-monosubstituted 2-alkenylanilines with solvent-dependence was demonstrated.

AB - A highly effective silver(I)-mediated C-H amination of 2-alkenylanilines has been developed to afford a diverse range of substituted indoles. High functional group tolerance, broad substrate scope, simple/fast/high-yielding reaction, and recovery/reuse of the inexpensive silver oxidant are noteworthy. Furthermore, an uncommon migratory process of β-monosubstituted 2-alkenylanilines with solvent-dependence was demonstrated.

KW - Cyclization

KW - Indoles

KW - Migration

KW - Oxidation

KW - Silver

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