Palladium-catalyzed asymmetric hydrosilylation of 1,3-dienes

Jin Wook Han, Tamio Hayashi

Research output: Contribution to journalReview article

29 Citations (Scopus)

Abstract

Advances in the palladium-catalyzed asymmetric hydrosilylation of 1,3-dienes are presented according to substrate types and chiral monophosphine ligands. Chiral monodentate phosphine ligands with a binaphthyl moiety have been proven to be the most efficient ligands for cyclic 1,3-dienes, and planar chiral ferrocenylmonophosphine ligands with two ferrocenyl moieties for linear 1,3-dienes. The ferrocenylmonophosphine ligands have expanded the substrate scope to 1,3-enynes in the asymmetric hydrosilylation. Palladium-catalyzed asymmetric hydrosilylation of 1,3-dienes and 1,3-enynes leads to the stereoselective synthesis of allylsilanes and allenylsilanes, respectively.

Original languageEnglish
Pages (from-to)2193-2197
Number of pages5
JournalTetrahedron Asymmetry
Volume21
Issue number18
DOIs
StatePublished - 2010 Sep 27

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Hydrosilylation
Palladium
dienes
palladium
Ligands
ligands
phosphine
Substrates
phosphines
synthesis

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Han, Jin Wook ; Hayashi, Tamio. / Palladium-catalyzed asymmetric hydrosilylation of 1,3-dienes. In: Tetrahedron Asymmetry. 2010 ; Vol. 21, No. 18. pp. 2193-2197.
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Palladium-catalyzed asymmetric hydrosilylation of 1,3-dienes. / Han, Jin Wook; Hayashi, Tamio.

In: Tetrahedron Asymmetry, Vol. 21, No. 18, 27.09.2010, p. 2193-2197.

Research output: Contribution to journalReview article

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