Microwave-Assisted Synthesis of Graphene-SnO2 Nanocomposites and Their Applications in Gas Sensors

Hyoun Woo Kim, Han Gil Na, Yong Jung Kwon, Sung Yong Kang, Myung Sik Choi, Jae Hoon Bang, Ping Wu, Sang Sub Kim

Research output: Contribution to journalArticle

54 Scopus citations

Abstract

We obtained extremely high and selective sensitivity to NO2 gas by fabricating graphene-SnO2 nanocomposites using a commercial microwave oven. Structural characterization revealed that the products corresponded to agglomerated structures of graphene and SnO2 particles, with small secondary SnOx (x ≤ 2) nanoparticles deposited on the surfaces. The overall oxygen atomic ratio was decreased with the appearance of an SnOx (x < 2) phase. By the microwave treatment of graphene-SnO2 nanocomposites, with the graphene promoting efficient transport of the microwave energy, evaporation and redeposition of SnOx nanoparticles were facilitated. The graphene-SnO2 nanocomposites exhibited a high sensor response of 24.7 for 1 ppm of NO2 gas, at an optimized temperature of 150 °C. The graphene-SnO2 nanocomposites were selectively sensitive to NO2 gas, in comparison with SO2, NH3, and ethanol gases. We suggest that the generation of SnOx nanoparticles and the SnOx phase in the matrix results in the formation of SnO2/SnO2 homojunctions, SnO2/SnOx (x < 2) heterojunctions, and SnO2/graphene heterojunctions, which are responsible for the excellent sensitivity of the graphene-SnO2 nanocomposites to NO2 gas. In addition, the generation of surface Sn interstitial defects is also partly responsible for the excellent NO2 sensing performance observed in this study.

Original languageEnglish
Pages (from-to)31667-31682
Number of pages16
JournalACS Applied Materials and Interfaces
Volume9
Issue number37
DOIs
StatePublished - 2017 Sep 20

Keywords

  • NO sensing
  • SnO
  • gas sensor
  • graphene
  • microwave-irradiation

Fingerprint Dive into the research topics of 'Microwave-Assisted Synthesis of Graphene-SnO<sub>2</sub> Nanocomposites and Their Applications in Gas Sensors'. Together they form a unique fingerprint.

  • Cite this