Hydrothermal synthesis of layered Li[Ni0.5Mn0.5] O2 as lithium intercalation material

Seung Taek Myung, Myung Hoon Lee, Sang Ho Park, Yang-Kook Sun

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Abstract

In attempt to synthesize layered Li[Ni0.5Mn0.5]O 2, a hydrothermal method has been employed. First, the spherical powder precursor, [Ni0.5Mn0.5](OH)2, was prepared via a coprecipitation. Then, the precursor was hydrothermally reacted with an excess amount of LiOH aqueous solution at 170°C for 4 days. From X-ray diffraction investigation, it was found that the hydrothermally prepared powders showed the layered Li[Ni0.5Mn0.5]O2 having α-NaFeO2 structure (space group: R3m). The as-prepared powders delivered the initial discharge of about 104 mAh g-1. Further calcination of the hydrothermally prepared powders at 800°C resulted in the well-ordered layered structure, indicating increase in the crystallinity. Subsequently, the resulting discharge capacity was also improved, 142 mAh g -1 by applying a current density of 20 mA g-1 (1/8C) and the capacity retention was relatively good during cycling.

Original languageEnglish
Pages (from-to)818-819
Number of pages2
JournalChemistry Letters
Volume33
Issue number7
DOIs
StatePublished - 2004 Jul 5

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