High-strength graphene and polyacrylonitrile composite fiber enhanced by surface coating with polydopamine

Hyunsoo Kim, Rouhollah Jalili, Geoffrey M. Spinks, Gordon G. Wallace, Seon Jeong Kim

Research output: Contribution to journalArticle

15 Scopus citations


Carbon fibers are well-known reinforcing elements in advanced composites, but these materials remain expensive partly due to the complex processing methods used to form high strength and high modulus fibers. Graphene is seen as an alternative precursor for the formation of high strength carbon-based fibers. Here it is shown that the strength and modulus of graphene-based fibers are enhanced by incorporating a polyacrylonitrile (PAN) binder, surface coating with polydopamine (PDA) and through appropriate pyrolysis heat treatments. Fiber samples were prepared by a wet-spinning method such that the composition of liquid-crystalline graphene oxide (LCGO) and PAN could be varied over the full range. The maximum fiber mechanical strength (220 MPa) and modulus (19 GPa) occurred at a composition of LCGO (80 wt%) and PAN (20 wt%). The mechanical strength was further significantly increased to 526 MPa through pyrolysis of the LCGO/PAN fiber at 800 °C in a nitrogen atmosphere which caused carbonization of PAN. In addition, surface treatment of the LCGO/PAN fiber with PDA before carbonization improved the mechanical strength by an additional 40%.

Original languageEnglish
Pages (from-to)280-285
Number of pages6
JournalComposites Science and Technology
Publication statusPublished - 2017 Sep 8



  • Graphene oxide
  • High strength
  • Polyacrylonitrile
  • Pyrolysis
  • Surface coating

Cite this