Cycle-dependent Microstructural Changes of Silicon-Carbon Composite Anodes for Lithium-Ion Batteries

Myungbeom Sohn, Dong Geun Lee, Dong Jae Chung, Ayoung Kim, Hansu Kim

Research output: Contribution to journalArticle

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Abstract

Si-based high capacity anodes are of the utmost importance for advancing energy density of lithium-ion batteries. The major shortcoming of Si-based anodes, however, is their poor cycle performance. To solve this problem, it is essential to understand the failure mechanisms of both the Si-based anodes. In this work, we observe the cycle-dependent microstructural evolution of a SiC composite/graphite-blended electrode using ex situ scanning electron microscopy observations and corresponding cross-sectional elemental mapping images. We reveal that the Si particles become finer and spread through the whole electrode and act as an electrochemically active site for electrolyte decomposition reactions. This forms a solid electrolyte interphase layer on the surface of the Si particles during cycling. The resulting electrolyte decomposition products surrounding the Si particles are finely spread throughout the whole blended electrode. This cycle-dependent microstructural change is one of the main reasons for the poor capacity retention of the blended electrode.

Original languageEnglish
Pages (from-to)150-156
Number of pages7
JournalBulletin of the Korean Chemical Society
Volume40
Issue number2
DOIs
Publication statusPublished - 2019 Feb

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Keywords

  • Graphite-blended electrode
  • Lithium-ion battery
  • Si-C composite
  • Si-based anode
  • Solid electrolyte interphase accumulation

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